The easiest way to measure 5 V on 3.3 V analog input is to use a voltage divider. For precise measurements I think you'd need to use an external specialized IC (ADC) that communicates via a digital interface such as I2C or SPI.
Notes:
- Netduino cannot measure voltage higher than analog reference (Aref), which is limited to operating voltage, which is 3.3 V.
- Netduino 2 analog inputs are not 5 V tolerant, the absolute maximum allowed input voltage is 4 V.