if you can get the boards and solder qfp64 (thats the smallest stm32f4, they are up to 176pins) its relativly easy. just the crystal has to be the same than netduino so it can run netduino firmware.
when you do it yourself you can also use way more pins of the cip.
ive never done one myself.
the schematics are open source also, so you can look there what is used and connected to wich pin.